Download/Embed scientific diagram | Diagrama de Pourbaix del hierro [12] y voltaje en función del pH (línea azul). from publication: Síntesis de nanopartículas. Download scientific diagram | Diagrama de Pourbaix para especies de cloro considerando una [Cl-] TOT = mM a T = 25°C para la ferrita de manganeso . ESPECIE. ΔG° (cal/mol). Pb. 0. PbO. , Pb3O4. , Pb2O3. , PbO2. , Pb2+. -5, Pb4+. 72, H2O. , REACCIONES DE.

Author: Kagor Nenris
Country: Liechtenstein
Language: English (Spanish)
Genre: Music
Published (Last): 20 May 2018
Pages: 284
PDF File Size: 4.75 Mb
ePub File Size: 14.90 Mb
ISBN: 501-7-96312-133-9
Downloads: 13201
Price: Free* [*Free Regsitration Required]
Uploader: Tojajar

Pourbaix diagrams have several uses, for example in corrosion studies, geoscience and in environmental studies. They thus give a guide to the stability of a particular metal in a specific environment.

Archived from the original on Sometimes additional lines are drawn for other concentrations. The diagrams also do not take kinetic effects into account, meaning that species shown as unstable might not react to any significant degree in practice. In these cases, pE is used instead of E H. Using the expressions for the free diagrammas in terms of potentials, the energy balance is given by a Nernst equation:. As such a Pourbaix diagram can be read diagramqs like a standard phase diagram with a different set of axes.

Pourbaix diagrams are widely used to describe the chemical behaviour of chemical species in the hydrosphere. Using the Pourbaix diagram correctly will help shed light not only on the nature of the species present in the solution or sample but may also help to understand the reaction mechanism. The same values should be used for all species present in the system. The reaction equation is found to be:. Wikimedia Commons has media related to Pourbaix diagrams.


Diagarmas this line, water will be reduced to hydrogen, and it will usually not be possible to pass beyond this line as long as there is still water present to be reduced.

Pourbaix diagram

In order to draw the position of the lines with the Nernst equation, the activity of the chemical species at equilibrium must be defined. The lines in the Pourbaix diagram show the equilibrium conditions, ds is, where the activities are equal, for the species on each side of that line.

Archived copy as title Commons category link is on Wikidata.

Passivation occurs when the metal forms a stable coating of an pouurbaix or other salt on its surface, the best example being the relative stability of aluminium because of the alumina layer formed on its surface when exposed to air. United States Government Printing Office.

The “H” stands for hydrogen, although other standards may be used, and they are for room temperature only. The reaction equation may be written:.

On either side of the line, one form of the species will instead be said to be predominant. The reaction equation is:. As a function of temperature. There are three types of line boundaries in a Pourbaix diagram: The equation must be balanced for M, H, O and charge. From Wikipedia, dizgramas free encyclopedia.

For instance, carbonate has a great effect upon the diagram for uranium. While such diagrams can be drawn for any chemical system, it is important to note that the addition of a metal binding agent ligand will often modify the diagram.

The reaction equation is written:.


Diagrama de Pourbaix – Viquipèdia, l’enciclopèdia lliure

Predominant ion boundaries are represented by lines. In other projects Wikimedia Commons. In addition, changes in temperature and concentration of solvated ions in solution will shift the equilibrium lines in accordance with the Nernst equation.

The diagrams are named after Marcel Pourbaix —the Russian -born, Belgian chemist who invented them.

See diagrams at right. By using this site, you agree dr the Terms of Use and Privacy Policy. Usually, the activity of a species is approximated as equal to the concentration for soluble species or partial pressure for gases. Vertical, horizontal, and sloped. Immunity means that the metal is not attacked, while corrosion shows that general attack will occur.

Pourbaix diagram – Wikipedia

Retrieved from ” https: A base-balanced equation can be converted to an acid-balanced equation using the equilibrium constant for the self-ionization of waterand only acid-balanced equations are considered below. Views Read Edit View history. Pourbaix diagrams are also known as E H -pH diagrams due to the labeling of the two axes. Geological Survey water-Supply Paper A simplified Pourbaix diagram indicates regions of “Immunity”, “Corrosion” and “Passivity”, instead of the stable species.

The vertical axis is labeled E H for the voltage potential with pourbsix to the standard hydrogen electrode SHE as calculated by the Nernst equation.